Synthesis and Electrochemical Performance of Polypyrrole- Coated Iron Oxide/Carbon Nanotube Composites
نویسندگان
چکیده
Copyright © Korean Carbon Society http://carbonlett.org Abstract In this work, iron oxide (Fe3O4) nanoparticles were deposited on multi-walled carbon nanotubes (MWNTs) by a simple chemical coprecipitation method and Fe3O4-decorated MWNTs (Fe-MWNTs)/polypyrrole (PPy) nanocomposites (Fe-MWNTs/PPy) were prepared by oxidation polymerization. The effect of the PPy on the electrochemical properties of the FeMWNTs was investigated. The structures characteristics and surface properties of MWNTs, Fe-MWNTs, and Fe-MWNTs/PPy were characterized by X-ray diffraction and X-ray photoelectron spectroscopy, respectively. The electrochemical performances of MWNTs, FeMWNTs, and Fe-MWNTs/PPy were determined by cyclic voltammetry and galvanostatic charge/discharge characteristics in a 1.0 M sodium sulfite electrolyte. The results showed that the Fe-MWNTs/PPy electrode had typical pseudo-capacitive behavior and a specific capacitance significantly greater than that of the Fe-MWNT electrode, indicating an enhanced electrochemical performance of the Fe-MWNTs/PPy due to their high electrical properties.
منابع مشابه
Chemical versus electrochemical synthesis of carbon nano-onion/polypyrrole composites for supercapacitor electrodes.
The development of high-surface-area carbon electrodes with a defined pore size distribution and the incorporation of pseudo-active materials to optimize the overall capacitance and conductivity without destroying the stability are at present important research areas. Composite electrodes of carbon nano-onions (CNOs) and polypyrrole (Ppy) were fabricated to improve the specific capacitance of a...
متن کاملPreparation of polymer coated superparamagnetic Iron Oxide (Fe3O4) nanoparticles for biomedical application
Biomedical applications of superparamagnetic iron oxide nanoparticles (SPIONs) requiring precise control over their physical and magnetic properties, and proper surface treatment. Here we report a practical and effective electrochemical strategy for preparation of the polymer coated SPIONs. In this strategy, in situ polymer coating on the surface of SPIONs was achieved through electrodeposition...
متن کاملPreparation of polymer coated superparamagnetic Iron Oxide (Fe3O4) nanoparticles for biomedical application
Biomedical applications of superparamagnetic iron oxide nanoparticles (SPIONs) requiring precise control over their physical and magnetic properties, and proper surface treatment. Here we report a practical and effective electrochemical strategy for preparation of the polymer coated SPIONs. In this strategy, in situ polymer coating on the surface of SPIONs was achieved through electrodeposition...
متن کاملDetection of napropamide by microwave resonator sensor using carbon nanotube – polypyrrole- chitosan layer
This paper presents the design and fabrication of proximity coupled feed disk resonator coated with Multi Walled Carbon Nanotubes (MWCNTs) and Polypyrrole-Chitosan (PPy-CHI) layers as a napropamide sensor. Computer Simulation Technology (CST) microwave studio was used to obtain the best design of disk resonator and feed line position in 5 GHz resonant frequency. Also, MWCNTs - PPy-CHI layers we...
متن کاملA Facile Synthesis of Polypyrrole/Carbon Nanotube Composites with Ultrathin, Uniform and Thickness-Tunable Polypyrrole Shells
An improved approach to assemble ultrathin and thickness-tunable polypyrrole (PPy) films onto multiwall carbon nanotubes (MWCNTs) has been investigated. A facile procedure is demonstrated for controlling the morphology and thickness of PPy film by adding ethanol in the reaction system and a possible mechanism of the coating formation process is proposed. The coated PPy films can be easily tuned...
متن کامل